Step 1: The formula for eccentricity \( e \) of an ellipse is given by:
\[
e = \sqrt{1 - \frac{b^2}{a^2}},
\]
where \( a \) is the length of the major axis and \( b \) is the length of the minor axis.
Step 2: Given that \( a = 3b \), we substitute into the formula and calculate the eccentricity to be \( e = \frac{2\sqrt{2}}{3} \).
Final Answer:
\[
\boxed{\frac{2\sqrt{2}}{3}}
\]