Step 1: Understanding the most stable conformation of n-butane.
In the most stable conformation of n-butane, the two methyl groups are positioned in the anti conformation, where the dihedral angle between them is maximized to reduce steric hindrance.
Step 2: Analyzing the torsional angle.
In the anti conformation, the dihedral angle between the two methyl groups is 180°.
Step 3: Conclusion.
The dihedral angle is \( \boxed{180^\circ} \).
