Question:

The compound which forms acetaldehyde when heated with dilute NaOH, is

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Geminal dihalides $\xrightarrow{OH^-}$ Carbonyl compounds.
Updated On: Apr 10, 2026
  • 1, 1-dichloroethane
  • 1, 1, 1-trichloroethane
  • 1-chloroethane
  • 1, 2-dichloroethane
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The Correct Option is A

Solution and Explanation

Step 1: Nucleophilic Substitution
Heating 1,1-dichloroethane with dilute NaOH replaces both chlorine atoms with hydroxyl (-OH) groups.
Step 2: Unstable Intermediate

The resulting gem-diol (two -OH groups on the same carbon) is highly unstable.
Step 3: Dehydration

The unstable gem-diol immediately loses a water molecule to form acetaldehyde ($CH_{3}CHO$).
Final Answer: (a)
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