Step 1: Understanding the Concept:
For a charged particle to move undeflected in a straight line, the net force on it must be zero.
Step 2: Detailed Explanation:
The Lorentz force is $\mathbf{F} = q(\mathbf{E} + \mathbf{v} \times \mathbf{B})$. For no deflection, $\mathbf{F} = 0$, so $\mathbf{E} = -(\mathbf{v} \times \mathbf{B})$. This implies $E = vB$ and $\mathbf{E}$ is perpendicular to both $\mathbf{v}$ and $\mathbf{B}$. Since $\mathbf{v}$ is along the line of motion, $\mathbf{E}$ and $\mathbf{B}$ are perpendicular to each other.
Step 3: Final Answer:
Thus $\mathbf{E} = \nu \mid \mathbf{B}$ and the two fields are perpendicular.