Concept:
Aryl halides like chlorobenzene do not undergo \(S_N1\) easily because formation of phenyl carbocation is highly unstable.
Step 1: Identify aryl halide.
\[
C_6H_5Cl
\]
is chlorobenzene.
Step 2: Reason for no \(S_N1\).
For \(S_N1\), carbocation formation is required. Phenyl carbocation is unstable and not formed easily.
Step 3: Conclusion.
Thus, chlorobenzene does not undergo hydrolysis by \(S_N1\) mechanism.