Concept:
For cubic crystals, angle between two directions \([u_1v_1w_1]\) and \([u_2v_2w_2]\) is:
\[
\cos\theta=\frac{u_1u_2+v_1v_2+w_1w_2}{\sqrt{u_1^2+v_1^2+w_1^2}\sqrt{u_2^2+v_2^2+w_2^2}}
\]
Step 1: Write the directions.
\[
[111]\quad \text{and}\quad [001]
\]
\[
u_1=1,\ v_1=1,\ w_1=1
\]
\[
u_2=0,\ v_2=0,\ w_2=1
\]
Step 2: Substitute values.
\[
\cos\theta=\frac{1(0)+1(0)+1(1)}{\sqrt{1^2+1^2+1^2}\sqrt{0^2+0^2+1^2}}
\]
\[
\cos\theta=\frac{1}{\sqrt{3}\times1}
\]
\[
\cos\theta=\frac{1}{\sqrt{3}}
\]
\[
\theta=\cos^{-1}\left(\frac{1}{\sqrt{3}}\right)
\]
\[
\therefore \text{Correct Answer is (D)}
\]