As soils weather over time, phosphorus (P) concentration declines steadily (monotonically), while nitrogen (N) follows a unimodal pattern. The key observation here is that nitrogen increases, reaches a peak, and then decreases, while phosphorus declines continuously. This suggests that the N:P ratio will initially rise as nitrogen increases relative to phosphorus in the younger soils, then reach a peak, and finally decrease as both nitrogen and phosphorus concentrations decline.
[6pt]
Graph (i) shows a similar trend where the N:P ratio increases initially (as N rises relative to P) and then decreases over time, which aligns with the observed patterns of nitrogen and phosphorus in the soils.
[6pt]
- Graph (ii) shows a constant N:P ratio, which does not fit the expected trend.
- Graph (iii) and (iv) show linear increases and decreases, which do not align with the unimodal pattern of nitrogen.
Thus, the correct diagram is (i), showing the expected changes in N:P ratio over the soil's age.