Question:

Presence of deoxy sugar in cardiac glycosides is identified by _____ test

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Keller-Kiliani = "K"ardiac Glycoside "K"arbohydrate (Deoxy sugar).
  • Raymond's
  • Shinoda
  • Kedde's
  • Killer Kiliani
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The Correct Option is D

Solution and Explanation

Step 1: Concept
Cardiac glycosides (like Digitoxin) contain unique 2,6-deoxy sugars such as digitoxose.

Step 2: Meaning

Specific chemical tests target either the sugar part or the lactone ring of the glycoside.

Step 3: Analysis

Raymond's, Kedde's, and Baljet's tests identify the unsaturated lactone ring. The Keller-Kiliani test specifically detects the presence of deoxy sugars, yielding a reddish-brown ring that turns blue-green.

Step 4: Conclusion

Therefore, the Keller-Kiliani test is the standard for identifying deoxy sugars in cardiac glycosides.

Final Answer: (D)
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