Concept:
Metabolic pathways and biochemical structures are governed by specific enzymes and environmental conditions. Understanding the differences between plant and animal storage molecules, as well as enzyme kinetics, is essential.
Step 1: Evaluate each biochemical statement.
• Statement A: Correct. Humans lack the enzyme cellulase required to break the $\beta$-1,4-glycosidic bonds in cellulose.
• Statement B: Incorrect. Enzymes are biological catalysts that increase the rate of reaction by lowering activation energy; they do not shift the equilibrium position of a reaction.
• Statement C: Correct. The Tricarboxylic Acid (TCA) cycle, or Krebs cycle, occurs in the mitochondria and requires oxygen (aerobic conditions) to process acetyl-CoA.
• Statement D: Incorrect. While glycogen is a branched polymer of glucose, it is the storage form in animals and fungi, not plants. The branched storage form in plants is amylopectin (a component of starch).
Step 2: Conclusion.
Based on the analysis, only statements A and C are scientifically accurate within the provided options. (Note: Standard biochemical knowledge indicates D is incorrect for plants, though it is often grouped as a branched glucose polymer).