Step 1: Write the formula for osmotic pressure.
\[
\pi = CRT
\]
Step 2: Substitute the given values.
\[
C = 1\,\text{M}, \quad R = 0.082\,\text{L atm K}^{-1}\text{mol}^{-1}, \quad T = 27 + 273 = 300\,\text{K}
\]
Step 3: Calculate osmotic pressure.
\[
\pi = 1 \times 0.082 \times 300 = 24.6\,\text{atm}
\]
Step 4: Conclusion.
Thus, the osmotic pressure is \(24.6\,\text{atm}\).