Question:

One mole of $A(g)$ was taken in a 1L closed flask and heated to T(K). At equilibrium, the concentration of $A(g)$ is equal to four times the equilibrium concentration of $B(g)$. What is $K_c$ for $A(g) \rightleftharpoons B(g) + C(g)$?

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Always define the equilibrium expression clearly from the balanced equation.
Updated On: Jun 6, 2026
  • 0.02
  • 0.04
  • 0.05
  • 0.06
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The Correct Option is C

Solution and Explanation

Step 1: Concept
Equilibrium constant $K_c = [B][C] / [A]$.

Step 2: Meaning
Let $[B] = y$. Then $[A] = 4y$. Initial moles = 1. $[A]_{eq} = 1 - x$, $[B] = x$, $[C] = x$. Given $[A] = 4[B]$, so $1 - x = 4x \implies 5x = 1 \implies x = 0.2$. $[A] = 0.8$, $[B] = 0.2$, $[C] = 0.2$.

Step 3: Analysis
$K_c = (0.2 \times 0.2) / 0.8 = 0.04 / 0.8 = 0.05$.

Step 4: Conclusion
The value of $K_c$ is 0.05.

Final Answer: (C)
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