Question:

Most strained cycloalkane is:

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Smallest ring = Largest strain (Angle = 60$^\circ$).
Updated On: May 25, 2026
  • Cyclopropane
  • Cyclobutane
  • Cyclohexane
  • Cyclopentane
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The Correct Option is A

Solution and Explanation

Step 1: Concept
Ring strain (Baeyer strain) occurs when the bond angles in a cyclic molecule deviate from the ideal tetrahedral angle of 109.5$^\circ$.

Step 2: Meaning

Higher deviation results in higher potential energy and lower stability.

Step 3: Analysis

In cyclopropane, the bond angles are forced to be 60$^\circ$. This deviation of 49.5$^\circ$ is the largest among the common cycloalkanes listed.

Step 4: Conclusion

Due to the extreme angle strain and torsional strain, cyclopropane is the most strained and reactive. Final Answer: (A)
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