Concept:
Band gap determines electrical conductivity of materials.
Step 1:
Conductors have:
\[
0~eV
\]
band gap.
Insulators have very large band gap:
\[
7~eV
\]
Step 2:
Silicon has band gap:
\[
1.12~eV
\]
\[
C \rightarrow IV
\]
Step 3:
Germanium has band gap:
\[
0.67~eV
\]
\[
D \rightarrow III
\]
Step 4:
\[
A-II,\quad B-I,\quad C-IV,\quad D-III
\]
\[
\boxed{\text{Correct Option = (1)}}
\]