Question:

Lucas reagent is

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The Lucas test is based on the formation of an insoluble alkyl chloride layer.
Updated On: Apr 24, 2026
  • Con. HNO\(_3\) + ZnCl\(_2\)
  • Con. HCl + ZnCl\(_2\)
  • Con. H\(_2\)SO\(_4\) + ZnCl\(_2\)
  • Acetic acid + ZnCl\(_2\)
  • Oleium + ZnCl\(_2\)
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The Correct Option is B

Solution and Explanation

Step 1: Understanding the Concept:
Lucas reagent is a chemical test used to distinguish between primary, secondary, and tertiary alcohols.
Step 2: Detailed Explanation:
Lucas reagent is a solution of anhydrous zinc chloride (ZnCl2) in concentrated hydrochloric acid (HCl). It reacts with alcohols to form alkyl chlorides. The rate of reaction is: tertiary > secondary > primary. Tertiary alcohols react immediately, secondary alcohols react within a few minutes, and primary alcohols react very slowly or not at all at room temperature.
Step 3: Final Answer:
Lucas reagent is conc. HCl + ZnCl2.
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