Step 1: Use the Central Limit Theorem.
Since \( X_1, X_2, \dots, X_{100} \) are i.i.d. random variables with mean 0 and variance \( \sigma^2 \), by the Central Limit Theorem, the sum \( S \) will be approximately normally distributed with mean 0 and variance \( 100\sigma^2 \).
Step 2: Standardizing the variable.
We standardize \( S \) by converting it to the standard normal form:
\[
Z = \frac{S - 0}{\sqrt{100 \sigma^2}} = \frac{S}{10\sigma}.
\]
We are given that \( P(S \leq 30) = 0.9332 \), so we look up the corresponding Z-value for a probability of 0.9332 in the standard normal table. This corresponds to a Z-value of approximately 1.5.
Step 3: Solve for \( \sigma \).
Now we solve for \( \sigma \) using:
\[
1.5 = \frac{30}{10\sigma} \quad \Rightarrow \quad \sigma = \frac{30}{15} = 2.
\]
Thus, \( \sigma^2 = 4 \).
Step 4: Conclusion.
Thus, \( \sigma^2 = 4 \).