Step 1: Understanding the Question:
The problem compares the work done to create two different soap bubbles. The first bubble has a radius $r$ and is blown at room temperature. The second bubble has its radius doubled to $2r$, but is blown from a solution that has been heated. We need to determine the correct inequality relation between the work values $W_1$ and $W_2$.
Step 2: Key Formula or Approach:
1. A soap bubble has two free surfaces (an inner and an outer surface). The work done ($W$) to form a bubble of radius $R$ against surface tension ($T$) is equal to the increase in surface energy:
$$W = 2 \times T \times \Delta A = 2 \times T \times (4\pi R^2) = 8\pi R^2 T$$
2. Surface tension is temperature-dependent: heating a liquid decreases its cohesive molecular forces, causing its surface tension coefficient to drop ($T_{\text{hot}} < T_{\text{cold}}$).
Step 3: Detailed Explanation:
Let's write down the expression for the first bubble blown at room temperature ($T_1$):
$$W_1 = 8\pi r^2 T_1$$
Now write down the expression for the second bubble blown from the heated solution, where radius $R = 2r$ and surface tension drops to $T_2$:
$$W_2 = 8\pi (2r)^2 T_2 = 8\pi (4r^2) T_2 = 4 \cdot (8\pi r^2 T_2)$$
Let's take the ratio of $W_2$ to $W_1$:
$$\frac{W_2}{W_1} = \frac{4 \cdot (8\pi r^2 T_2)}{8\pi r^2 T_1} = 4 \left(\frac{T_2}{T_1}\right)$$
$$W_2 = 4W_1 \left(\frac{T_2}{T_1}\right)$$
Since the soap solution was heated for the second bubble, its temperature increased. Because surface tension decreases with rising temperature, we know that:
$$T_2 < T_1 \implies \frac{T_2}{T_1} < 1$$
Substituting this inequality boundary constraint into our equation reveals that:
$$W_2 < 4W_1$$
Step 4: Final Answer:
The work done for the second bubble satisfies the condition $W_2 < 4W_1$, matching option (D).