Step 1: Recall Rolle’s Theorem.
If a function \(f'(x)\) is continuous on \([a,b]\) and differentiable on \((a,b)\), and if \(f'(a) = f'(b)\),
then there exists a point \(c \in (a,b)\) such that \(f''(c) = 0\).
Step 2: Apply the theorem to the given condition.
Given \(f\) is twice differentiable, \(f'\) is differentiable and hence continuous on \([0,1]\).
Also, \(f'(0) = f'(1)\).
Therefore, by Rolle’s theorem, there exists \(c \in (0,1)\) such that \(f''(c) = 0\).
Step 3: Examine other options.
(A) Continuity of \(f''\) is not guaranteed by twice differentiability; it only ensures \(f''\) exists.
(C) \(f'\) need not be bounded on an arbitrary interval without extra conditions.
(D) Similarly, \(f''\) may not be bounded on \((0,1)\).
Final Answer:
\[
\boxed{(B)}
\]