Step 1: Understanding pollen storage concept.
Pollen banks are facilities where pollen grains are preserved for long-term use in plant breeding and conservation programs.
Step 2: Requirement for preservation.
Pollen grains must be stored at extremely low temperatures to maintain viability and prevent metabolic activity.
Step 3: Role of liquid nitrogen.
Liquid nitrogen provides a temperature of about -196°C, which effectively halts all biological activity, making it ideal for long-term pollen storage.
Step 4: Analysis of other options.
Sodium alginate and sugar solutions are used in tissue culture techniques, not long-term pollen storage. Liquid hydrogen is not used in biological preservation.
Step 5: Final evaluation.
Only liquid nitrogen satisfies the requirement for cryopreservation of pollen grains.
Step 6: Final conclusion.
Thus, the correct answer is liquid nitrogen.
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\boxed{(4)}
\]