Question:

Intramolecular hydrogen bond is present in

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o-nitrophenol is steam volatile due to intramolecular H-bonding.
Updated On: Apr 27, 2026
  • phenol
  • o-nitrophenol
  • p-nitrophenol
  • o-cresol
  • p-cresol
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The Correct Option is B

Solution and Explanation

Step 1: Concept
Intramolecular H-bonding occurs within the same molecule.

Step 2: Meaning

It requires a hydrogen donor and acceptor in close proximity.

Step 3: Analysis

In ortho-nitrophenol, the $-OH$ and $-NO_2$ groups are adjacent, allowing them to form a hydrogen bond.

Step 4: Conclusion

Hence, the correct answer is o-nitrophenol.
Final Answer: (B)
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