Step 1: Concept
Intramolecular H-bonding occurs within the same molecule.
Step 2: Meaning
It requires a hydrogen donor and acceptor in close proximity.
Step 3: Analysis
In ortho-nitrophenol, the $-OH$ and $-NO_2$ groups are adjacent, allowing them to form a hydrogen bond.
Step 4: Conclusion
Hence, the correct answer is o-nitrophenol.
Final Answer: (B)