In the following reaction sequence,
The major product B is :
The major product B is :
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The Correct Option is B
Solution and Explanation
Step 2: Br2/AcOH is an electrophilic aromatic substitution. Ring substituents: NHCOCH3 (strong activator, o/p) and CH3 (weak activator, o/p).
Step 3: The stronger activating group (NHCOCH3) controls the position. Its para position is occupied by CH3, so Br enters ortho to NHCOCH3 (position 2).
Step 4: B = N-(2-bromo-4-methylphenyl)acetamide. Meta bromination (option A) is not expected; acylation (option C) needs Friedel-Crafts conditions; benzylic bromination (option D) needs radical conditions (light/NBS).
Answer: (B)
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