Concept:
Group 13 elements (B, Al, Ga, In, Tl) show distinct trends in thermal properties and metallic character as we move down the group.
Step 1: Identify elements Y and Z.
Gallium (Ga) has the lowest melting point among Group 13 elements (Z).
Thallium (Tl) has a relatively low boiling point in its elemental form compared to others (Y).
Step 2: Analyze the nature of their oxides.
The oxide of Thallium (\(Tl_2O\)) is basic in nature.
The oxide of Gallium (\(Ga_2O_3\)) is amphoteric in nature.
\[
\boxed{\text{Basic, amphoteric}}
\]