Step 1: Adsorption is exothermic.
Adsorption releases energy, so \(\Delta H < 0\).
Step 2: Disorder decreases.
Gas molecules get immobilized on the surface, reducing randomness, so \(\Delta S < 0\).
Step 3: Final conclusion.
Hence, thermodynamic requirement is:
\[
\boxed{\Delta H = -ve, \, \Delta S = -ve}
\]