Question:

In adsorption, the thermodynamic requirement is:

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Adsorption is generally exothermic and decreases entropy of the system.
Updated On: Jun 19, 2026
  • \(\Delta H = +ve\); \(\Delta S = +ve\)
  • \(\Delta H = -ve\); \(\Delta S = -ve\)
  • \(\Delta H = -ve\); \(\Delta S = +ve\)
  • \(\Delta H = +ve\); \(\Delta S = -ve\)
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The Correct Option is B

Solution and Explanation

Step 1: Adsorption is exothermic.
Adsorption releases energy, so \(\Delta H < 0\).

Step 2: Disorder decreases.

Gas molecules get immobilized on the surface, reducing randomness, so \(\Delta S < 0\).

Step 3: Final conclusion.

Hence, thermodynamic requirement is: \[ \boxed{\Delta H = -ve, \, \Delta S = -ve} \]
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