Concept:
Three vectors are coplanar if their scalar triple product is zero.
\[
\vec{A}\cdot(\vec{B}\times\vec{C}) = 0
\]
Equivalently, the determinant formed by their components is zero.
Step 1: Write vectors in component form.
\[
\vec{A} = (2,-1,1)
\]
\[
\vec{B} = (1,2,-3)
\]
\[
\vec{C} = (3,a,5)
\]
Step 2: Form the determinant condition.
\[
\begin{vmatrix}
2 & -1 & 1
1 & 2 & -3
3 & a & 5
\end{vmatrix} = 0
\]
Step 3: Expand the determinant.
\[
= 2
\begin{vmatrix}
2 & -3
a & 5
\end{vmatrix}
- (-1)
\begin{vmatrix}
1 & -3
3 & 5
\end{vmatrix}
+ 1
\begin{vmatrix}
1 & 2
3 & a
\end{vmatrix}
\]
\[
= 2(10 + 3a) + (5 + 9) + (a - 6)
\]
\[
= 20 + 6a + 14 + a - 6
\]
\[
= 28 + 7a
\]
Since vectors are coplanar:
\[
28 + 7a = 0
\]
\[
a = -4
\]
\[
\boxed{a = -4}
\]