Step 1: Understanding the Concept:
Perform matrix multiplication row by column and equate to the given result.
Step 2: Detailed Explanation:
Row 1, col 1: $a(1)+2(3)+3(-1) = a+3 = 4 \Rightarrow a = 1$.
Row 2, col 1: $b(1)+5(3)+(-1)(-1) = b+16 = 12 \Rightarrow b = -4$.
Step 3: Final Answer:
$(a, b) = (1, -4)$.