Concept:
Transpose of a matrix is obtained by interchanging rows and columns.
If:
\[
A+A^T=I
\]
then corresponding elements of matrices must be equal.
Step 1: Find transpose of \(A\).
Given:
\[
A=
\begin{bmatrix}
\sin\alpha & -\cos\alpha
\cos\alpha & \sin\alpha
\end{bmatrix}
\]
Therefore:
\[
A^T=
\begin{bmatrix}
\sin\alpha & \cos\alpha
-\cos\alpha & \sin\alpha
\end{bmatrix}
\]
Step 2: Compute \(A+A^T\).
\[
A+A^T
=
\begin{bmatrix}
2\sin\alpha & 0
0 & 2\sin\alpha
\end{bmatrix}
\]
Given:
\[
A+A^T=I
\]
Therefore:
\[
\begin{bmatrix}
2\sin\alpha & 0
0 & 2\sin\alpha
\end{bmatrix}
=
\begin{bmatrix}
1 & 0
0 & 1
\end{bmatrix}
\]
Hence:
\[
2\sin\alpha=1
\]
\[
\sin\alpha=\frac12
\]
Step 3: Use the interval condition.
General solutions:
\[
\alpha=\frac{\pi}{6},\frac{5\pi}{6}
\]
But:
\[
\alpha\in\left(\frac{\pi}{2},\frac{3\pi}{2}\right)
\]
Only:
\[
\boxed{
\alpha=\frac{5\pi}{6}
}
\]
satisfies the interval.
Step 4: Final conclusion.
\[
\boxed{
\frac{5\pi}{6}
}
\]
Hence correct option is:
\[
\boxed{(2)}
\]