Step 1: Understanding the Concept
Aspirin is acetylsalicylic acid. It is made by acetylating the phenolic -OH of salicylic acid with acetic anhydride.
Step 2: Structure
The benzene ring carries a -COOH group and, on the adjacent (ortho) carbon, an acetoxy group \(\text{-OCOCH}_{3}\). It is 2-acetoxybenzoic acid.
Step 3: Compare with similar compounds
The ring with -OH and -COOH is salicylic acid, the ring with -OH and \(\text{-COOCH}_{3}\) is methyl salicylate, and the ring with two \(\text{-COOCH}_{3}\) groups is dimethyl phthalate.
Final Answer:
Aspirin is the structure with ortho -COOH and -OCOCH3 groups.
\[ \boxed{\text{(C) }\text{Structure with ortho -COOH and -OCOCH}_{3}\text{ groups}} \]