Step 1: Understanding the Concept
Plutonium (Z = 94) is an actinoid. In early actinoids the 5f, 6d and 7s levels are close in energy, so many electrons take part in bonding.
Step 2: Oxidation states
Plutonium shows the oxidation states \(+3, +4, +5, +6\) and \(+7\).
Step 3: Conclusion
The maximum among these is \(+7\).
Final Answer:
The highest oxidation state of plutonium is +7.
\[ \boxed{\text{(D) }+7} \]