Question:

Identify from following physical transformations that exhibits decrease in entropy.

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Entropy decreases when matter goes from a more disordered state to a more ordered one, such as gas to liquid.
Updated On: Nov 13, 2026
  • \(\mathrm{H}_{2}\mathrm{O}_{(\mathrm{s})}\longrightarrow \mathrm{H}_{2}\mathrm{O}_{(l)}\)
  • \(\mathrm{H}_{2}\mathrm{O}_{(l)}\longrightarrow \mathrm{H}_{2}\mathrm{O}_{(\mathrm{g})}\)
  • \(\mathrm{H}_{2}\mathrm{O}_{(\mathrm{s})}\longrightarrow \mathrm{H}_{2}\mathrm{O}_{(\mathrm{g})}\)
  • \(\mathrm{H}_{2}\mathrm{O}_{(\mathrm{g})}\longrightarrow \mathrm{H}_{2}\mathrm{O}_{(\ell )}\)
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The Correct Option is D

Solution and Explanation

Step 1: Understanding the Concept
Entropy measures disorder. Gas \(\gt\) liquid \(\gt\) solid in entropy.

Step 2: Check each change
Solid to liquid, liquid to gas and solid to gas all increase disorder, so entropy increases.

Step 3: Condensation
Gas to liquid, \(\text{H}_2\text{O}_{(g)} \rightarrow \text{H}_2\text{O}_{(l)}\), makes the molecules more ordered, so \(\Delta S\) is negative.

Final Answer:
Condensation of water vapour shows a decrease in entropy. \[ \boxed{\text{(D) }\text{H}_2\text{O}_{(g)}\longrightarrow\text{H}_2\text{O}_{(l)}} \]
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