Question:

Which of the following processes has \(\Delta S\) negative?

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Entropy falls when the disorder of the system decreases, such as a gas being held on a solid surface.
Updated On: Oct 1, 2026
  • Dissolving Sugar in Water
  • Adsorption of a Gas on a Solid Surface
  • \(2\text{NH}_3(g)\rightarrow \text{N}_2(g)+3\text{H}_2(g)\)
  • Sublimation of Dry Ice
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The Correct Option is B

Solution and Explanation

Step 1: Understanding the Concept:
Entropy measures disorder. A process that makes the system more ordered has \(\Delta S < 0\).

Step 2: Check option (A).
Sugar dissolving in water spreads out the sugar molecules, so disorder increases and \(\Delta S > 0\).

Step 3: Check option (B).
In adsorption a gas molecule that moved freely gets held on a surface. Its freedom drops, so \(\Delta S < 0\).

Step 4: Check option (C).
\(2\text{NH}_3 \to \text{N}_2 + 3\text{H}_2\) increases gas moles from 2 to 4, so \(\Delta S > 0\).

Step 5: Check option (D).
Sublimation of dry ice turns a solid into a gas, a huge rise in disorder, so \(\Delta S > 0\).

Final Answer:
Only adsorption of a gas on a solid has a negative \(\Delta S\), option (B). \[ \boxed{\text{(B)}} \]
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