Step 1: Understanding the Concept
Isomorphous substances are different compounds that crystallise in the same structure and have a similar formula type.
Step 2: Check the pairs
Diamond and fullerene are allotropes of carbon. \(\beta\)-quartz and cristobalite are forms of silica. Calcite and aragonite are polymorphs of \(\text{CaCO}_3\). These are the same substance in different forms, not isomorphs.
Step 3: Sodium fluoride and magnesium oxide
\(\text{NaF}\) and \(\text{MgO}\) both have a 1:1 ratio and crystallise in the rock-salt (face-centred cubic) structure.
Step 4: Compare the options
So the isomorphous pair is option (C).
Final Answer:
Sodium fluoride and magnesium oxide are isomorphous.
\[ \boxed{\text{(C) }\text{Sodium fluoride and Magnesium oxide}} \]