Question:

Fructose on reduction gives a mixture of two alcohols which are related as:

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• Epimers differ at only one chiral carbon • All epimers are diastereomers
Updated On: Mar 19, 2026
  • diastereomers
  • epimers
  • both (a) and (b)
  • anomers
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The Correct Option is C

Solution and Explanation


Step 1:
Fructose is a ketohexose. On reduction, the carbonyl group (C=O) is reduced to an alcohol.
Step 2:
Reduction of fructose gives two hexitols: sorbitol and mannitol.
Step 3:
Sorbitol and mannitol differ in configuration at one chiral carbon (C-2). ⟹ They are epimers and hence diastereomers
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