Question:

Freundlich adsorption isotherm fails at which of the following conditions?

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Freundlich isotherm is suitable for low to moderate pressures and heterogeneous surfaces.
Updated On: Jun 26, 2026
  • High temperature
  • Low temperature
  • High pressure
  • Low pressure
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The Correct Option is C

Solution and Explanation

Step 1: Understand Freundlich isotherm.
It is an empirical relation that assumes adsorption on heterogeneous surfaces.

Step 2: Analyze temperature effect.
High temperature reduces adsorption but Freundlich equation is still valid qualitatively.

Step 3: Analyze pressure effect.
At high pressure, adsorption saturates and the isotherm fails to represent the plateau.

Step 4: Low pressure.
At low pressures, the Freundlich equation works well since adsorption is proportional to pressure.

Step 5: Conclusion.
Freundlich isotherm fails at high pressure.
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