Step 1: Coordination Number Definition.
The coordination number of a metal atom or ion in a coordination compound is the number of ligands directly bonded to it. It indicates the number of coordination bonds formed between the metal ion and the surrounding ligands.
Step 2: Example.
In the complex \( [Co(NH_3)_6]^{3+} \), the coordination number of the central metal ion \( Co^{3+} \) is 6 because it is surrounded by six ammonia molecules \((NH_3)\), which are the ligands.
Step 3: Conclusion.
Thus, the coordination number is an important feature in coordination compounds and is determined by the number of ligands attached to the central metal atom.
(i) Draw the diagram which indicates the splitting of d-orbitals in tetrahedral field.
(ii) Write any one limitation of valence bond theory.
(i)[Ni(CN)₄]²⁻ and [Ni(CO)(_4)] have different structures, but do not differ in their magnetic behaviour. Explain.
(ii) Write the formula of Tetraamineaquachloridocobalt(III)chloride.
(i) Write two postulates of Werner's coordination theory.
(ii) Draw the geometrical isomers of [(NH_3)_3(NO_2)_3] and give their structures.