Write the IUPAC names of the following coordination compound: \([Co(NH_3)_6]Cl_3\)
Step 1: Identify the ligands. The ligand in this compound is ammonia \((NH_3)\), which is a neutral ligand.
Step 2: Identify the oxidation state of the metal. Cobalt (Co) in this compound is in the +3 oxidation state, because the three chloride ions \((Cl^-)\) each carry a -1 charge, and the six ammonia molecules are neutral. Thus, the total charge on the complex is +3.
Step 3: Write the IUPAC name. The IUPAC name is: Hexaamminecobalt(III) chloride.
(i) Draw the diagram which indicates the splitting of d-orbitals in tetrahedral field.
(ii) Write any one limitation of valence bond theory.
(i)[Ni(CN)₄]²⁻ and [Ni(CO)(_4)] have different structures, but do not differ in their magnetic behaviour. Explain.
(ii) Write the formula of Tetraamineaquachloridocobalt(III)chloride.
(i) Write two postulates of Werner's coordination theory.
(ii) Draw the geometrical isomers of [(NH_3)_3(NO_2)_3] and give their structures.