Question:
Coordination number of Fe in the complexes [Fe(CN)\(_6\)]\(^{4-}\), [Fe(CN)\(_6\)]\(^{3-}\) and [FeCl\(_4\)]\(^{-}\) would be respectively:
Coordination number of Fe in the complexes [Fe(CN)\(_6\)]\(^{4-}\), [Fe(CN)\(_6\)]\(^{3-}\) and [FeCl\(_4\)]\(^{-}\) would be respectively:
Show Hint
In coordination complexes, the coordination number corresponds to the number of ligands bonded to the central metal ion.
Updated On: Apr 22, 2026
- 6, 4, 6
- 6, 6, 4
- 6, 3, 3
- 2, 3, 3
Show Solution
Verified By Collegedunia
The Correct Option is B
Solution and Explanation
Step 1: Understanding the coordination number.
Coordination number refers to the number of ligands directly bonded to the central metal ion in a complex.
Step 2: Explanation of the options.
- (1) 6, 4, 6: This is not correct, as the coordination number for [FeCl\(_4\)]\(^{-}\) is 4, not 6.
- (2) 6, 6, 4: This is correct. [Fe(CN)\(_6\)]\(^{4-}\) and [Fe(CN)\(_6\)]\(^{3-}\) both have coordination number 6, and [FeCl\(_4\)]\(^{-}\) has coordination number 4.
- (3) 6, 3, 3: This is incorrect for the given complexes.
- (4) 2, 3, 3: This is incorrect for all three complexes.
Step 3: Conclusion.
The correct answer is (2) 6, 6, 4.
Coordination number refers to the number of ligands directly bonded to the central metal ion in a complex.
Step 2: Explanation of the options.
- (1) 6, 4, 6: This is not correct, as the coordination number for [FeCl\(_4\)]\(^{-}\) is 4, not 6.
- (2) 6, 6, 4: This is correct. [Fe(CN)\(_6\)]\(^{4-}\) and [Fe(CN)\(_6\)]\(^{3-}\) both have coordination number 6, and [FeCl\(_4\)]\(^{-}\) has coordination number 4.
- (3) 6, 3, 3: This is incorrect for the given complexes.
- (4) 2, 3, 3: This is incorrect for all three complexes.
Step 3: Conclusion.
The correct answer is (2) 6, 6, 4.
Was this answer helpful?
0
0
Top MET Chemistry Questions
- Which of the following product is formed in the reaction $ CH_3MgBr {->[(i)CO_2][(ii)H_2O]} ? $
- Ethyl chloride is converted into diethyl ether by:
- Correct order of reactivity:
- A group of 13 element if added in small amounts to Ge, then the type of semiconductor formed is
- Consider the following statements I. Repulsive forces are significant when the molecules are close together on average. II. Attractive intermolecular forces are important when the molecules are fairly close together but not necessarily touching. III. Attractive forces are ineffective when the molecules are for apart. Select correct statements.
View More Questions
Top MET coordination compounds Questions
- In which of the following complex ion, the central metal ion is in a state of \( sp^{3}d^{2} \) hybridisation?
- The number of significant figures in the numbers $4.8000 \times 10^4$ and 48000.50 are respectively
- Match List-I (Compound) with List-II (Hybridisation): List-I & List-II
A. \( \text{CuCl}_5^{3-} \) & I. \( sp^3d^2 \)
B. \( \text{MnCl}_5^{3-} \) & II. \( d^2sp^3 \)
C. \( \text{XeOF}_4 \) & III. \( dsp^3 \)
D. \( \text{Fe(CO)}_5 \) & IV. \( sp^3d \)
Choose the correct match: - The spin only magnetic moment of $[NiCl_4]^{2-}$ is_ _ _ _ (Nearest integer).
- The oxidation state of Cr in \([Cr(H_2O)_6]Cl_3\), \([Cr(C_6H_6)_2]\), \(K_2[Cr(CN)_2(O)_2(O_2)(NH_3)]\) respectively are:
View More Questions
Top MET Questions
- A coil of 100 turns and area $2 \times 10^{-2}m^2 $ is pivoted about a vertical diameter in a uniform magnetic field and carries a current of 5A. When the coil is held with its plane in north-south direction, it experiences a couple of 0.33 Nm. When the plane is east-west, the corresponding couple is 0.4 Nm, the value of magnetic induction is [Neglect earth's magnetic field]
- $\int\limits_{0}^{8}| x -5| d x$ is equal to
- Radiation, with wavelength 6561 $?$ falls on a metal surface to produce photoelectrons. The electrons are made to enter a uniform magnetic field of $3 \times 10^{-4} T$. If the radius of the largest circular path followed by the electrons is 10 mm, the work function of the metal is close to :
- In intrinsic semiconductor at room temperature number of electrons and holes are
- Which of the following product is formed in the reaction $ CH_3MgBr {->[(i)CO_2][(ii)H_2O]} ? $
View More Questions