Question:

Consider the following \[ \begin{aligned} \text{I.} \quad & \text{1-Bromo-1-phenylpropane} \\ \text{II.} \quad & \text{1-Bromo-3-}\mathit{n}\text{-butyl-2-methylbenzene} \end{aligned} \] Bromides I and II are classified respectively as

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\textbf{Benzylic halide:} Halogen attached to the carbon adjacent to a benzene ring. \textbf{Aryl halide:} Halogen directly attached to the benzene ring.
Updated On: Jul 9, 2026
  • Benzyl ; Aryl
  • Aryl ; Aryl
  • Primary ; Benzyl
  • Aryl ; Primary \bigskip
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The Correct Option is A

Solution and Explanation

Step 1: Classify Bromide I. The structure of 1-bromo-1-phenylpropane is \[ \mathrm{C_6H_5-CH(Br)-CH_2-CH_3} \] Here, the bromine atom is attached to the carbon adjacent to the benzene ring (benzylic carbon). Hence, Bromide I is a \[ \boxed{\text{Benzyl bromide}.} \]

Step 2:
Classify Bromide II. In 1-bromo-3-n-butyl-2-methylbenzene, the bromine atom is directly attached to the benzene ring. Such compounds are classified as \[ \boxed{\text{Aryl halides}.} \]

Step 3:
Final conclusion. Therefore, \[ \boxed{\text{I -- Benzyl,\qquad II -- Aryl}} \] Hence, the correct option is \(\boxed{(A)}\).
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