Step 1: Understanding the Concept:
This question tests basic knowledge of semiconductor physics and p-n junctions.
Step 2: Detailed Explanation:
1. Statement A: Incorrect. Intrinsic semiconductors are pure. Semiconductors with impurities are called extrinsic.
2. Statement B: Incorrect. Pure Ge/Si are intrinsic semiconductors.
3. Statement C: Incorrect. In semiconductors, conductivity increases as temperature increases (negative temperature coefficient of resistance).
4. Statement D: Incorrect. Rectifiers are primary applications of p-n junction diodes.
5. Statement E: Correct. In forward bias, the external voltage opposes the potential barrier, narrowing the depletion region and reducing the barrier height.
Step 3: Final Answer:
The potential barrier in a forward biased p-n junction gets reduced.