Concept:
Pollen-pistil interaction involves a series of well-defined steps from pollination to fertilization in flowering plants.
Step 1: Identify the first event.
Pollination begins with the deposition of pollen grains on the stigma.
\[
\text{First step: Deposition of pollen (iii)}
\]
Step 2: Understand pollen germination.
After reaching the stigma, the pollen grain germinates and forms a pollen tube.
\[
\text{Next step: Development of pollen tube (ii)}
\]
Step 3: Entry into ovule.
The pollen tube grows through the style and enters the ovule via the synergid.
\[
\text{Next step: Entry into synergid (i)}
\]
Step 4: Final event.
The pollen tube releases its contents (male gametes) into the embryo sac.
\[
\text{Final step: Release of contents (iv)}
\]
Step 5: Conclusion.
Thus, the correct sequence is:
\[
\text{iii} \rightarrow \text{ii} \rightarrow \text{i} \rightarrow \text{iv}
\]