Concept:
Chloroquine is an antimalarial drug. Chemically, it is a 4-aminoquinoline derivative.
Step 1: Understanding chloroquine structure.
Chloroquine contains a quinoline nucleus. The chlorine atom is attached to the quinoline ring.
Step 2: Position of chlorine.
In chloroquine, the chlorine substituent is present at the \(7^{th}\) position of the quinoline ring.
Step 3: Importance of structure.
The quinoline ring and its substituents are important for the antimalarial activity of chloroquine.
Step 4: Checking options.
The chlorine is not at the \(2^{nd}\), \(4^{th}\), or \(8^{th}\) position. It is specifically at the \(7^{th}\) position.
Step 5: Final answer.
Therefore, chloroquine contains chlorine at the \(7^{th}\) position.
\[
\boxed{7^{th}}
\]