Step 1: Path to A
Benzene + $H_{2}SO_{4} \rightarrow$ Benzene sulphonic acid (A).
Step 2: Path to B
Alkali fusion of (A) converts the $-SO_{3}H$ group into a hydroxyl group, giving Phenol (B).
Step 3: Path to C
Phenol reacts with excess bromine water ($Br_{2}/H_{2}O$) to undergo poly-substitution.
Step 4: Conclusion
The final product C is 2, 4, 6-tribromophenol.
Final Answer: (D)