Step 1: Understand minimum deviation condition.
The lowest point in deviation curve corresponds to minimum deviation condition.
Step 2: Recall the symmetry condition.
At minimum deviation:
\[
i = e
\]
where \( i \) is angle of incidence and \( e \) is angle of emergence.
Step 3: Explain physical reason.
Light travels symmetrically through the prism at minimum deviation.
Step 4: Relation of internal angles.
Angles of refraction inside prism become equal:
\[
r_1 = r_2
\]
Step 5: Use standard prism relation.
\[
A = r_1 + r_2 \Rightarrow r_1 = r_2 = \frac{A}{2}
\]
Step 6: Key conclusion.
Symmetry implies:
\[
i = e
\]
Step 7: Final conclusion.
Thus,
\[
\boxed{i = e}
\]
Therefore, the correct option is
\[
\boxed{(3)\ \text{angle of emergence}}
\]