Concept:
The convective mass transfer coefficient ($k_m$) is analogous to the heat transfer coefficient. It characterizes the rate of mass transfer between a moving fluid and a surface or another phase.
Step 1: Evaluate Assertion A.
The mass transfer coefficient is a function of system geometry, fluid velocity, and physical properties such as density, viscosity, and molecular diffusivity. This is typically represented by dimensionless correlations like $Sh = f(Re, Sc)$. Thus, Assertion A is correct.
Step 2: Evaluate Reason R.
Mass transfer occurs through a concentration boundary layer. The thickness of this boundary layer ($\delta_c$) is determined by the flow conditions (velocity and turbulence). A thinner boundary layer results in less resistance and a higher mass transfer coefficient. Thus, Reason R is correct.
Step 3: Establish the connection.
The mass transfer coefficient is influenced by velocity and properties precisely because those factors determine the boundary layer's characteristics. Therefore, R is the correct explanation for A.