Step 1: Understanding the Concept:
Ammonium fertilizers affect soil pH.
The mechanism involves nitrification.
Step 2: Key Formula or Approach:
No specific formula.
Need to understand the acidification process.
Step 3: Detailed Explanation:
Prolonged use of ammonium fertilizers causes acidification.
This is due to the release of H\(^+\) ions during nitrification.
Ammonium (NH\(_4^+\)) is converted to nitrate (NO\(_3^-\)).
This process releases H\(^+\) ions.
However, the reason given (accumulation of nitrate ions) is not the cause of acidification.
The acidification is due to H\(^+\) release, not nitrate accumulation.
Thus, A is correct, but R is not correct.
Step 4: Final Answer:
A is correct but R is not correct.
Hence, the correct option is (C).