Step 1: Thiophanate-methyl is a systemic fungicide used against fungal diseases, so (A) matches (III) Fungicide. Step 2: Atrazine is a triazine herbicide used to kill weeds, so (B) matches (I) Weedicide. Step 3: Fenamiphos is an organophosphate nematicide used against plant-parasitic nematodes, so (C) matches (IV) Nematicide. Step 4: Afidopyropen is an insecticide used mainly against sap-sucking insects like aphids, so (D) matches (II) Insecticide. This gives (A)-(III), (B)-(I), (C)-(IV), (D)-(II), which is option 2.