A. Phenyl methanamine
B. N,N-Dimethylaniline
C. N-Methyl aniline
D. Benzenamine
Choose the correct order of basic nature of the above amines.
B. N,N-Dimethylaniline
C. N-Methyl aniline
D. Benzenamine
Choose the correct order of basic nature of the above amines.
Show Hint
- D > C > B > A
- A > C > B > D
- D > B > C > A
- A > B > C > D
The Correct Option is D
Solution and Explanation
The others are aromatic amines whose lone pair is delocalised into the ring. Electron-donating methyl groups on N increase the basicity: \(pK_b\) values are N,N-dimethylaniline 8.94 (B), N-methylaniline 9.15 (C), aniline 9.38 (D).
Order of basic strength: A > B > C > D.
Answer: (4) A > B > C > D
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