Step 1: Use the shunt resistor formula.
The shunt resistor \( R_s \) is given by:
\[
R_s = \frac{V}{I} - R_{\text{mv}}
\]
where \( V \) is the voltage range of the ammeter, \( I \) is the current range, and \( R_{\text{mv}} \) is the resistance of the voltmeter.
Step 2: Apply the formula.
Substituting the values:
\[
R_s = \frac{25}{25} - 0.025 = 0.001 \, \Omega
\]
Final Answer:
\[
\boxed{0.001 \, \Omega}
\]