Step 1: Understanding the condition.
We are given that the perimeter of triangle ABC is 6 times the arithmetic mean of the sines of its angles. The perimeter \( P \) of triangle ABC is:
\[
P = a + b + c.
\]
The arithmetic mean of the sines of the angles is:
\[
\frac{\sin A + \sin B + \sin C}{3}.
\]
Step 2: Equation setup.
The problem tells us that:
\[
P = 6 \times \frac{\sin A + \sin B + \sin C}{3}.
\]
Substitute \( P = a + b + c \) into the equation:
\[
a + b + c = 2 (\sin A + \sin B + \sin C).
\]
Step 3: Substituting \( a = 1 \) and simplifying.
We know that \( a = 1 \). So the equation becomes:
\[
1 + b + c = 2 (\sin A + \sin B + \sin C).
\]
Step 4: Using known identities.
We know that \( \sin A + \sin B + \sin C \) is maximized when \( A = B = C = \frac{\pi}{3} \). Substituting \( A = \frac{\pi}{3} \) into the equation, we find that:
\[
\sin A + \sin B + \sin C = 3 \times \sin \frac{\pi}{3} = 3 \times \frac{\sqrt{3}}{2}.
\]
Step 5: Solving for \( \angle A \).
Solving the equation for \( A \), we get \( \angle A = \frac{\pi}{3} \).
Final Answer:
The correct value of \( \angle A \) is:
\[
\boxed{\frac{\pi}{3}}.
\]