Concept:
Isomers have the same molecular formula but different structures.
Step 1: Find formula of 3-methylbut-1-yne.
3-methylbut-1-yne has 5 carbon atoms and formula:
\[
C_5H_8
\]
Step 2: Check option A.
2,3-Dimethylbuta-1,3-diene has 6 carbon atoms, so its formula is not \(C_5H_8\).
Step 3: Conclusion.
Therefore, it is not an isomer of 3-methylbut-1-yne.