Question:

Which one of the following is an ambidentate ligand? ________.

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Ambidentate ligands lead to linkage isomerism in coordination compounds.
Updated On: Jun 26, 2026
  • Oxalate
  • Carbon monoxide
  • Ethylene diamine
  • Ammonia
  • Nitrite
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The Correct Option is

Solution and Explanation

Step 1: Concept
An ambidentate ligand is a monodentate ligand that can coordinate to a metal center through two different atoms.

Step 2: Meaning

Common examples include $CN^-$, $SCN^-$, and $NO_2^-$.

Step 3: Analysis

Nitrite ($NO_2^-$) can bond through the Nitrogen atom (Nitrito-N) or through the Oxygen atom (Nitrito-O).

Step 4: Conclusion

Nitrite is the ambidentate ligand among the options. Final Answer: (E)
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