Question:

Which one of the following is an ambidentate ligand?

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Common ambidentate ligands: \(NO_2^-\), \(CN^-\), \(SCN^-\).
Updated On: Apr 29, 2026
  • \(Cl^-\)
  • \(H_2O\)
  • \(H_2NCH_2CH_2NH_2\)
  • \(SCN^-\)
  • \(C_2O_4^{2-}\)
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The Correct Option is D

Solution and Explanation

Concept: Ambidentate ligands can coordinate through two different donor atoms, but only one at a time.

Step 1:
Check \(SCN^-\).
Thiocyanate ion can bind through: \[ S \quad \text{or} \quad N \]

Step 2:
Identify ambidentate nature.
Since \(SCN^-\) can attach through two possible atoms, it is ambidentate.

Step 3:
Choose correct option.
Thus, the ambidentate ligand is: \[ SCN^- \]
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